Two-dimensional nematics in bulk and confined geometries
D. de las Heras, Y. Martínez-Ratón, L. Mederos, and E. Velasco
J. Mol. Liq., 185, 13, (2013) DOI: 10.1016/j.molliq.2012.08.014
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Abstract:
Two-dimensional nematics possess peculiar properties that have been studied recently using computer simulation and various theoretical models. Here we review our own contribution to the field using density-functional theory, and present some preliminary simulation results on confined two-dimensional nematics. First we discuss the possible stable bulk phases and phase diagrams and the relation between phases and particle geometry. We then explore the adsorption properties on a single substrate and the confinement effects that arise when the fluid is confined between parallel walls. Next, confinement in circular cavities is presented; this geometry allows us to measure some properties of the simplest defects that arise in two-dimensional nematics. Finally, preliminary Monte Carlo simulation results of confined nematics in circular geometry are shown.
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